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Photo-oxidation Of HDPE Geomembrane

Photo-oxidation Of HDPE Geomembrane

UV radiation is the primary aging threat to HDPE geomembranes in open-air projects (such as landfill caps and exposed reservoirs). Its essence is a light-induced oxidation chain reaction that causes polymer chain scission and embrittlement.
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Description

Products Description

 

UV radiation is the primary aging threat to HDPE geomembranes in open-air projects (such as landfill caps and exposed reservoirs). Its essence is a light-induced oxidation chain reaction that causes polymer chain scission and embrittlement. The service life of unmodified pure HDPE under unshielded UV exposure is less than 3 years, manifested as surface powdering, tensile strength loss of more than 30% and uncontrolled permeability. Photo-oxidation of HDPE geomembrane.Engineering practice extends the service life to more than 50 years by uniformly doping carbon black to construct a UV shielding layer - carbon black not only absorbs 99% of UV radiation, but also inhibits the spread of oxidation by quenching free radicals.

 

different thicknesses of Geomembranes

Test

Unit

Standard

Test
Frequency

RH75

RH10

RH15

RH20

RH30

Mechanical Properties

 

Thickness

mm

D5199

per roll

0.75

1.00

1.50

2.00

3.00

Density

g/cc

D1505/D792

90,000 kg

0.94

Tensile Properties

 

D 6693

           

· yield strength

kN/m

Type IV

9,000 kg

11

15

22

29

44

· break strength

kN/m

   

20

27

40

53

80

· yield elongation

%

   

12

12

12

12

12

· break elongation

%

   

700

700

700

700

700

Tear Resistance

N

D 1004

20,000 kg

93

125

187

249

374

Puncture Resistance

N

D 4833

20,000 kg

240

320

480

640

96

Geomembranes1294
Geomembranes1438

 

How does UV light "burn" geomembranes?

 

Imagine the plastic film is like a strong rope, and ultraviolet rays (UV) are scissors:

 

Step 1: Cut the crack

The UV-B rays in sunlight (similar to strong ultraviolet rays) cut the HDPE molecular chain, producing "free radical fragments".

 

Step 2: Fragments oxidize and rust

When the fragments meet the air, they are like iron sheets meeting water, and they "rust" (oxidation reaction) like crazy, turning into more fragile "peroxides".

 

Step 3: The rope breaks completely

These "rusty" fragments further decompose, eventually causing the plastic surface to powder and crack (just like the brittle cracking of an aged plastic raincoat).

Photo-oxidation of HDPE geomembrane

What happens to a "sunburned" geomembrane?

 

Become fragile: tensile strength decreases by 20-40% (like an aging rubber band that breaks when pulled)

 

Loss of elasticity: ductility decreases by more than 50% (similar to hardened rubber that cannot be stretched)

 

Surface cracking: hair-like cracks (0.1-0.5mm deep, such as cracks in dry land)

 

Risk of water leakage: cracks cause the anti-seepage performance to plummet by 10,000 times (like a bucket with a hole)

 

[ Unprotected HDPE membrane will fail within 3 years under the scorching sun!]

 

How to "sunscreen" geomembranes?

Core weapon: Carbon black (plastic "sunscreen")

Photo-oxidation of HDPE geomembrane

Protection points Working principle Compliance requirements
Additional amount Absorbs 99% of ultraviolet rays ≥2.0%
Particle fineness The finer the more uniform Particle size 20-25 nanometers
Dispersion Prevents agglomeration No agglomeration under a microscope

 

Contact

 

Tai'an City Ruiheng Building Materials Co., Ltd

● Address: NO.3566 Longquan Road, Tai'an Hi-tech Zone, Shandong Province, China

● Website: www.rhgeomembrane.com

● Email: bonnie@rhgeos.com

● Phone / Whatsapp / Wechat: 0086 188 5482 2179

 

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